Br in BrO3-(aq)AnswerN in N2O5(g)AnswerPb in Pb(SO4)2AnswerO in sodium peroxide (Na2O2)AnswerH in CaH2AnswerS in S2O32-(aq)
6 years ago
Answered By Leonardo F
For the first chemical compound, $I_{2\left(s\right)}$I2(s) , we have to remember that the oxidation number of each atom in a simple substance (only one chemical species) is 0. Hence, the oxidation number of I is 0.
For the second species, $HS^-$HS− , we know that in complex ions, the sum of the oxidation numbers of all the atoms is equal to the charge of the ion. The H atom has oxidation number of +1. Hence, we have:
$+1+x=-1$+1+x=−1
In which x is the oxidation number of S. Solving, we have: x=-2
Hence, oxidation number of S is -2.
Applying the same concept to the third compound, the oxidation number of F is -1. The sum of all the oxidation numbers in a molecule is 0. Hence:
6 years ago
Answered By Leonardo F
For the first chemical compound, $I_{2\left(s\right)}$I2(s) , we have to remember that the oxidation number of each atom in a simple substance (only one chemical species) is 0. Hence, the oxidation number of I is 0.
For the second species, $HS^-$HS− , we know that in complex ions, the sum of the oxidation numbers of all the atoms is equal to the charge of the ion. The H atom has oxidation number of +1. Hence, we have:
$+1+x=-1$+1+x=−1
In which x is the oxidation number of S. Solving, we have: x=-2
Hence, oxidation number of S is -2.
Applying the same concept to the third compound, the oxidation number of F is -1. The sum of all the oxidation numbers in a molecule is 0. Hence:
$x+6\left(-1\right)=0\rightarrow x=+6$x+6(−1)=0→x=+6
The oxidation number of Xe is +6.
In a simple ion, the oxidation number is always equal to the charge of the ion. Hence, for the $Sn^{4+}$Sn4+ , the oxidation number of Sn is +4.
For $BrO^{3-}$BrO3− , the oxidation number of O is -2. Hence:
$x+3\left(-2\right)=-1\rightarrow x=+5$x+3(−2)=−1→x=+5
The oxidation number of Br is +5. For $N_2O_5$N2O5 , the oxidation number of O is -2. Hence:
$2x+5\left(-2\right)=0\rightarrow x=+5$2x+5(−2)=0→x=+5
The oxidation number of N is +5. For $Pb\left(SO_4\right)_2$Pb(SO4)2 , the oxidation number of the anion sulfate ( $SO_4^{2-}$SO42− ) is -2. Hence:
$x+2\left(-2\right)=0\rightarrow x=+4$x+2(−2)=0→x=+4
The oxidation number of Pb is +4. For $Na_2O_2$Na2O2 , the O, in peroxides, has always an oxidation number of -1.
For $CaH_2$CaH2 , this is a metal hydride. The hydrogen has an oxidation number of -1.
For $S_2O_3^{2-}$S2O32− , the oxygen has an oxidation number of -2. Hence:
$2x+3\left(-2\right)=-2\rightarrow x=+2$2x+3(−2)=−2→x=+2
The oxidation number of S is +2.
Putting all the answers together:
$I$I in $I_2$I2 : 0
$S$S in $HS^-$HS− : -2
$Xe$Xe in $XeF_6$XeF6 : +6
$Sn$Sn in $Sn^{4+}$Sn4+ : +4
$Br$Br in $BrO_3^-$BrO3− : +5
$N$N in $N_2O_5$N2O5 : +5
$Pb$Pb in $Pb\left(SO_4\right)_2$Pb(SO4)2 : +4
$O$O in $Na_2O_2$Na2O2 : -1
$H$H in $CaH_2$CaH2 : -1
$S$S in $S_2O_3^{2-}$S2O32− : +2